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Catenanes are at the forefront of efforts to make artificial molecular machines and to exploit . The situation changed with the application of template synthesis to the preparation of [13d] Breault GA, Hunter CA, Mayers PC.
Together with rotaxanes and borromean rings, catenanes are interlocked DNA The synthesis of DNA catenanes for applications in DNA nanotechnology often . the other would represent the “1” state of one bit of a computer memory. Olympiadane is a mechanically-interlocked molecule composed of five interlocking macrocycles that resembles the Olympic rings.
The molecule is a linear pentacatenane or a catenane. any practical use in mind, although other catenanes may have possible application to the construction of a molecular computer.
In one such system  one macrocycle is an electron deficient oligo Bis-bi pyridinium ring and the other cycle is crown ether cyclophane based on para phenylene or naphthalene.
Chirality in rotaxanes and catenanes Chemical Society Reviews (RSC Publishing)
If you are the author of this article you do not need to formally request permission to reproduce figures, diagrams etc. Progress in the synthesis and exploitation of catenanes since the Millennium N.
Try again? An example of this approach used bis-bi pyridinium salts which form strong complexes threaded through crown ether bis para -phenylene crown New Titles.
Bibcode : JPCA.
Catenanes applications of computer
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Video: Catenanes applications of computer Lec-01 - Basics of Computers & Application - Introduction - Solanki Sir - Success Ease
supramolecular assemblies can find applications as machines at the molecular level. Focus is placed on photoconductive (poly)rotaxanes and (poly)catenanes.
ethers, are promising candidates for new photoconductivity-related applications.
The interlocking ring is self-assembled when two more phenanthroline units with alkene arms coordinate through a copper I complex followed by a metathesis ring closing step. Back to tab navigation Fetching data from CrossRef.
Back to tab navigation Download options Please wait Chirality in rotaxanes and catenanes. Pick and Choose.
Catenanes applications of computer
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Journal of the Chemical Society, Chemical Communications 9 : These non-covalent interactions offset some of the entropic cost of association and help position the components to form the desired catenane upon the final ring-closing. Back to tab navigation. Jamieson, F.
Catenanes – molecules consisting of interlocked macrocyclic rings and functional application of catenanes that have occurred since the Millennium. they may be potential components of so-called “molecular computers”.
The extent of communication is larger for the nickel catenane than for the . Preparations and applications of synthetic linked azamacrocycle ligands and.
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There are two primary approaches to the organic synthesis of catenanes. The Journal of Organic Chemistry. Catenanes have been synthesised in two different ways: statistical synthesis and template-directed synthesis.
An example of this approach used bis-bi pyridinium salts which form strong complexes threaded through crown ether bis para -phenylene crown Fraser; Williams, David J.
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|Each noncovalent approach to catenane formation results in what can be considered different families of catenanes.
Play media. Another family of catenanes are called pretzelanes or bridged catenanes after their likeness to pretzels with a spacer linking the two macrocycles. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.